PM6，PBDB-TF, 1802013-83-7, PBDB-T-2F, P型聚合物, 聚合物给体, polymeric donor

描述

Poly[[4,8-bis[5-(2-ethylhexyl)–4-fluoro-2-thienyl]benzo[1,2-b:4,5-b′]dithiophene-2,6-diyl]–2,5-thiophenediyl[5,7-bis(2-ethylhexyl)–4,8-dioxo-4H,8H–benzo[1,2-c:4,5-c′]dithiophene-1,3-diyl]–2,5-thiophenediyl] (ACI)

有机光电子聚合物给体材料PM6, PBDB-T-2F, PBDB-TF, PCE 20%+

Catalog No.: P9203

Molecular formula: (C₆₈H₇₆F₂O₂S₈)_n

CAS No.: 1802013-83-7     ;  CAS No.: 1802013-84-8 (from 2 monomers)

Other Names for this Substance:

• PBDB-T-2F
• PBDB-TF
• PM6
• PM 6

HOMO level: -5.45 eV

LUMO level: -3.60 eV

 

热门的有机太阳能电池给体材料。

我们提供两种品质的PM6：

标准批次的PM6与Y6制备器件的PCE>16%; （相同批次与IT-4F器件结果13.5%左右）

高品质批次的PM6与Y6制备器件的PCE在17%水平。可用于冲击有机太阳能电池高效率。（相同批次与IT-4F器件结果13.8%以上，部分批次超过14%，数量较少）

 

Structure: ITO/PEDOT:PSS/PBDB-T-2F+BTP-eC9/PDINO/Al

Reported:

Voc=0.839V, Jsc=26.20mA/cm2, FF=81.10%, PCE=17.80%

Adv Mater, 2020, 32: 1908205

1: A Large-Bandgap Conjugated Polymer for Versatile Photovoltaic Applications with High Performance; Advanced Materials (2015), 27(31), 4655-4660

Herein, we synthesized a new copolymer PM6 based on 4,8-bis(5-(2-ethylhexyl)-4-fluorothiophen-2-yl)benzo[1,2-b:4,5-b’]dithiophene(BDT-F) and 1,3-bis(thiophen-2-yl)-5,7-bis(2-ethylhexyl)benzo-[1,2-c:4,5-c’]dithiophene-4,8-dione (BDD). The optical, electrochem., and photovoltaic properties, the mol. packing pattern, and the morphol. of the blend lms were investigated. Compared with the nonfluorinated derivative PBDTBDD, PM6 exhibited a similar optical bandgap of 1.80 eV and a deeper HOMO level of -5.45 eV (-5.25 eV for PBDTBDD), which is beneficial for a high V_oc. BHJ PSCs based on PM6/PC71 BM with both conventional and inverted device structures were fabricated and showed promising photovoltaic performance: a high V_oc of 0.98 V and a PCE of 8% for the conventional devices and up to 9.2% for the inverted devices. Furthermore, the PM6/PC71BM based semitransparent device exhibited a PCE of 5.7%, which is among the highest values obtained for a semitransparent single-junction device. In addition, we found that the neat film of PM6 exhibited strong crystallinity and a dominant face on packing with respect to the electrodes, which is advantageous for charge transport. These results indicate that PM6 is a promising material for photovoltaic application.

2: 19.31% binary organic solar cell and low non-radiative recombination enabled by non-monotonic intermediate state transition; Nature Communications (2023), 14(1), 1760

3: Approaching 19% efficiency and stable binary polymer solar cells enabled by a solidification strategy of solvent additive; Science China: Chemistry (2023), 66(5), 1500-1510

4: High-Efficiency Binary Organic Solar Cells Enabled by Pseudo-Bilayer Configuration in Dilute Solution; Solar RRL (2023), 7(9), 2201090

5: High-performance and mechanically durable semi-transparent organic solar cells with highly transparent active layers; Science China Materials (2023), 66(5), 1719-1726

6: Over 18% efficiency ternary all-polymer solar cells with high photocurrent and fill factor; Matter (2023), 6(5), 1542-1554

7: Halogen-Free Donor Polymers Based on Dicyanobenzotriazole with Low Energy Loss and High Efficiency in Organic Solar Cells; Small (2023), 19(18), 2206607